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PEAR - Pioneering Exploration of Aluminium Reversibility for Advanced Hybrid Ion Capacitors

Duration:
01/12/2025 - 31/05/2027
Principal investigator(s):
Project type:
University research - Individual Projects
Funding body:
ATENEO
Project identification number:
10674
PoliTo role:
Sole Contractor

Abstract

The PEAR project (Pioneering Exploration of Aluminium Reversibility for Advanced Hybrid Ion Capacitors) aims to unlock a critical bottleneck in the development of sustainable, high-performance electrochemical energy storage technologies. While lithium-ion technologies dominate the current market, their reliance on scarce resources and environmental impact demands the development of alternative systems. Aluminium, the third most abundant element in the Earth’s crust, offers significant advantages: high volumetric capacity, low cost, excellent recyclability, and wide availability, particularly within the EU. However, a fundamental challenge persists: achieving efficient and reversible electrochemical deposition (plating) and dissolution (stripping) of Al3+ ions without relying on hazardous, alumino-halogenated electrolytes.

PEAR proposes a transformative approach by developing aluminium-based hybrid capacitors (HCs) that combine high energy and power densities. The core innovation targets the creation of an aluminophilic interface and chloro-aluminate free electrolytes capable of enabling reversible Al3+ electrochemistry. The project is structured around three key objectives: (1) activation of aluminium surfaces to overcome native oxide barriers and enable reversible Al3+ deposition; (2) formulation of stable, chloro-aluminate free electrolytes with optimized Lewis acidity; and (3) validation of these materials in prototype HCs to demonstrate feasibility and performance. A strong interdisciplinary methodology integrates surface science, electrochemistry, materials synthesis, and advanced characterization techniques (SEM, XPS, Raman, IR, NMR), supported by computational modelling and life cycle assessments. Results from PEAR will provide unprecedented insights into Al-ion interface chemistry, enabling efficient and safe storage technologies. By bridging the gap between batteries and supercapacitors, PEAR's Al-based HCs will serve applications ranging from electric vehicles to stationary grid storage. The project is aligned with EU priorities for circular economy and energy resilience. With aluminium recycling requiring only 5% of the energy of primary production, and Europe possessing a robust Al recycling infrastructure, PEAR is uniquely positioned to catalyze sustainable innovation. PEAR will also serve as a stepping stone toward the development of full Al-ion batteries and improved electroplating techniques, impacting sectors such as electronics, automotive, and aerospace. Beyond technical goals, PEAR commits to open science, inclusiveness, and industrial collaboration to accelerate the commercialization of EU-based, post-lithium energy solutions.

Structures

Keywords

ERC sectors

PE8_6 - Energy processes engineering
PE8_8 - Materials engineering (metals, ceramics, polymers, composites, etc.)

Sustainable Development Goals

Obiettivo 7. Assicurare a tutti l’accesso a sistemi di energia economici, affidabili, sostenibili e moderni|Obiettivo 12. Garantire modelli sostenibili di produzione e di consumo

Budget

Total cost: € 60,000.00
Total contribution: € 60,000.00
PoliTo total cost: € 60,000.00
PoliTo contribution: € 60,000.00